Visually striking layers of burnt orange, yellow, silver, brown and blue-tinged black are characteristic of banded iron formations, sedimentary rocks that may have prompted some of the largest volcanic eruptions in Earths history, according to new research from Rice University
The rocks contain iron oxides that sank to the bottom of oceans long ago, forming dense layers that eventually turned to stone. The study published this week in Nature Geoscience suggests the iron-rich layers could connect ancient changes at Earths surface like the emergence of photosynthetic life to planetary processes like volcanism and plate tectonics.
In addition to linking planetary processes that were generally thought to be unconnected, the study could reframe scientists understanding of Earths early history and provide insight into processes that could produce habitable exoplanets far from our solar system.
These rocks tell quite literally the story of a changing planetary environment, said Duncan Keller, the studys lead author and a postdoctoral researcher in Rices Department of Earth, Environmental and Planetary Sciences. They embody a change in the atmospheric and ocean chemistry.
Banded iron formations are chemical sediments precipitated directly from ancient seawater rich in dissolved iron. Metabolic actions of microorganisms, including photosynthesis, are thought to have facilitated the precipitation of the minerals, which formed layer upon layer over time along with chert (microcrystalline silicon dioxide). The largest deposits formed as oxygen accumulated in Earths atmosphere about 2.5 billion years ago.
These rocks formed in the ancient oceans, and we know that those oceans were later closed up laterally by plate tectonic processes, Keller explained.
The mantle, though solid, flows like a fluid at about the rate that fingernails grow. Tectonic plates continent-sized sections of the crust and uppermost mantle are constantly on the move, largely as a result of thermal convection currents in the mantle. Earths tectonic processes control the life cycles of oceans.
Just like the Pacific Ocean is being closed today its subducting under Japan and under South America ancient ocean basins were destroyed tectonically, he said. These rocks either had to get pushed up onto continents and be preserved and we do see some preserved, thats where the ones were looking at today come from or subducted into the mantle.
Because of their high iron content, banded iron formations are denser than the mantle, which made Keller wonder whether subducted chunks of the formations sank all the way down and settled in the lowest region of the mantle near the top of Earths core. There, under immense temperature and pressure, they would have undergone profound changes as their minerals took on different structures.
There's some very interesting work on the properties of iron oxides at those conditions, Keller said. They can become highly thermally and electrically conductive. Some of them transfer heat as easily as metals do. So its possible that, once in the lower mantle, these rocks would turn into extremely conductive lumps like hot plates.
Keller and his co-workers posit that regions enriched in subducted iron formations might aid the formation of mantle plumes, rising conduits of hot rock above thermal anomalies in the lower mantle that can produce enormous volcanoes like the ones that formed the Hawaiian Islands. Underneath Hawaii, seismological data show us a hot conduit of upwelling mantle, Keller said. Imagine a hot spot on your stove burner. As the water in your pot is boiling, youll see more bubbles over a column of rising water in that area. Mantle plumes are sort of a giant version of that.
We looked at the depositional ages of banded iron formations and the ages of large basaltic eruption events called large igneous provinces, and we found that theres a correlation, Keller said. Many of the igneous events which were so massive that the 10 or 15 largest may have been enough to resurface the entire planet were preceded by banded iron formation deposition at intervals of roughly 241 million years, give or take 15 million. Its a strong correlation with a mechanism that makes sense.
The study showed that there was a plausible length of time for banded iron formations to first be drawn deep into the lower mantle and to then influence heat flow to drive a plume toward Earths surface thousands of kilometers above.
In his effort to trace the journey of banded iron formations, Keller crossed disciplinary boundaries and ran into unexpected insights.
If whats happening in the early oceans, after microorganisms chemically change surface environments, ultimately creates an enormous outpouring of lava somewhere else on Earth 250 million years later, that means these processes are related and talking to each other, Keller said. It also means its possible for related processes to have length scales that are far greater than people expected. To be able to infer this, weve had to draw on data from many different fields across mineralogy, geochemistry, geophysics and sedimentology.
Keller hopes the study will spur further research. I hope this motivates people in the different fields that it touches, he said. I think it would be really cool if this got people talking to each other in renewed ways about how different parts of the Earth system are connected.
Keller is part of the CLEVER Planets: Cycles of Life-Essential Volatile Elements in Rocky Planets program, an interdisciplinary, multi-institutional group of scientists led by Rajdeep Dasgupta, Rices W. Maurice Ewing Professor of Earth Systems Science in the Department of Earth, Environmental and Planetary Sciences.
This is an extremely interdisciplinary collaboration thats looking at how volatile elements that are important for biology carbon, hydrogen, nitrogen, oxygen, phosphorus and sulfur behave in planets, at how planets acquire these elements and the role they play in potentially making planets habitable, Keller said.
Were using Earth as the best example that we have, but were trying to figure out what the presence or absence of one or some of these elements might mean for planets more generally, he added.
Cin-Ty Lee, Rices Harry Carothers Wiess Professor of Geology, Earth, Environmental and Planetary Sciences, and Dasgupta are co-authors on the study. Other co-authors are Santiago Tassara, an assistant professor at Bernardo OHiggins University in Chile, and Leslie Robbins, an assistant professor at the University of Regina in Canada, who both did postdoctoral work at Yale University, and Yale Professor of Earth and Planetary Sciences Jay Ague, Kellers doctoral adviser.
NASA (80NSSC18K0828) and the Natural Sciences and Engineering Research Council of Canada (RGPIN-2021-02523) supported the research.